Petrochemical, biofuel, and oil derivative compositional analysis with benchtop and handheld XRF

When it comes to compositional analysis of petrochemicals and biofuels, the main issue is accurately measuring the levels of regulated substances, such as sulfur and chlorine. Sulfur is controlled to extremely low levels and this can be difficult to detect. Elemental analysis is also crucial in the manufacture of products that are derived from petrochemicals. Lube oil, roofing shingles and polymers all rely on controlled additives to give them the desired performance characteristics.

XRF analysis is the established method for verifying levels of substances within fuels – both those that are unwanted and those that are added deliberately, and many of the regulations surrounding the production of fuels call for XRF analysis. Not every XRF instrument can detect the very low levels of sulfur within fuel and the instrument must be chosen carefully. Sometimes a handheld XRF instrument is necessary, especially when checking sulfur levels in marine oil.

Applications for XRF analysis in the petrochemical and fuel industry

  • Asphalt roofing shingles: XRF analysis is used in process control, specifically to measure the level of copper additive to meet final product specification.
  • Crude oil: Benchtop XRF analysis to determine levels of sulfur and chlorine, plus nickel, vanadium and iron need to be kept below a certain level.
  • Polymers derived from naphtha: Process control of polymers derived from naphtha is routinely carried out by XRF, including detection of titanium, zinc, calcium and magnesium.
  • Bunker fuel oil and factory fuel: Benchtop and handheld XRF analysis to ensure compliance with the stringent low sulfur levels in bunker fuel oil.
  • Diesel fuels for heavy vehicles and machinery: XRF used at various stages throughout the distillation and catalytic hydrotreatment processes to verify and control sulfur limits.
  • Jet fuel: XRF analysis to meet industry regulations for sulfur of jet fuel, including aviation fuel with biofuel in the blend.
  • Automotive and biofuels: As well as checking for regulated levels of sulfur in biofuel / fossil fuel blends, XRF is also used to check sulfur and chlorine levels in recycled cooking oil.
  • Lubricating oil: XRF used extensively to control levels of additives in the mix for high performance blends.

LAB-X5000 benchtop XRF for reliable, accurate quality control

LAB-X5000 benchtop XRF for reliable, accurate quality control

The powerful LAB-X5000 is ideal for verifying levels of sulfur, chlorine and metals within crude oil, lubricants, and fuel oils. Its rugged and compact design is ideal for use in a busy production environment, and a sample spinner makes it easy to make several measurements to ensure homogeneity. Complete with safety window to protect against any spillages, the LAB-X is the workhorse of many labs and petrochemical testing facilities worldwide.

X-Supreme8000 benchtop XRF for ultra-low sulfur analysis

X-Supreme8000 benchtop XRF for ultra-low sulfur analysis

The X-Supreme8000 is the analyzer to choose if you have a lot of samples to test and need to detect ultra-low levels of sulfur. The analyzer includes a ten-position autosampler and once up to ten samples are loaded into the instrument, it can be left to automatically measure each one. The X-Supreme will detect low levels of sulfur and chlorine, as well as nickel, vanadium, and iron in fuel oils.

X-MET8000 handheld XRF analyzer for bunker fuel oil analysis

X-MET8000 handheld XRF analyzer for bunker fuel oil analysis

The X-MET8000 is a handheld analyzer that is designed for on-site analysis. As a portable device with a long battery life and embedded GPS to pinpoint location of analysis performed, the X-MET is ideal for on-board testing of sulfur within marine fuel. This lightweight, durable instrument is tested to the MIL-STD-810G standard for robustness and conforms to ASTM D4294, ISO8754 and IP336.

Wilhelmsen and Hitachi High-Tech Analytical Science partnership

Watch how the X-MET8000 analyzer is an essential piece of on-board equipment for IMO2020 compliance

See Hitachi analyzers in action

Watch how the LAB-X, X-Supreme and X-MET can support petrochemical and fuel production and quality control.

Learn how XRF analysis can support the petrochemical and fuel industry

Analyzing the content of manganese in motor and aviation gasoline

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High performance analysis of lubricating oil with the LAB-X5000

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Elemental analysis of crude oil with X-ray fluorescence (XRF)

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Achieve laboratory-standard testing on board your ship

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Take a look at our resource library for more on the petrochemical and fuel industry.

Brochures and application notes

To find out more about XRF analysis in general, and how our instruments can support your specific application, you can download the relevant brochure or application note below.

Contact us for expert advice

For more information on the best instrument for your petrochemical or fuel application, get in touch to speak with one of our experts.

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